Polybond Ltd. Unit 6, William Street, Northam, Southampton, SO14 5QH Tel: 02380 988350    Fax: 02380 988355

Q19 - Health and Safety Datasheet 1. IDENTIFICATION OF SUBSTANCE Product Name Polybond Q19 Product Description A two part epoxy polyamide resin paint dispersed in water Supplier As heading   2.1 CLASSIFICATION OF THE SUBSTANCES OR MIXTURE EC 1272/2008 Physical and Chemical Hazards None Human health Eye Irr. 2 - H319, Skin Irr. 2 - H315 Environment None 1999/45/EEC Xi Eye Irr - R36/38 The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. Human health The product causes serious eye and skin irritation. Physical and Chemical Hazards None 2.2 LABEL ELEMENTS Contains Isopropanol Linseed oil, polymer w bis. A, bis. A diglycidyl ether,diethylenetriamine, formaldehyde, glycidyl Ph ether and pentaethylenehexamine Labels in Accordance with EC 1272/2008 Signal Word Warning Hazard Statements H315 Causes skin irritation. H319 Causes serious eye irritation. Precautionary Statements P280 Wear protective gloves/protective clothing/eye protection/face protection. P301 + P310 IF SWALLOWED: Immediately call a doctor. P331 Do NOT induce vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS     *Linseed oil, polymer w bis. A, bis. A diglycidyl ether,diethylenetriamine, formaldehyde, glycidyl Ph ether and pentaethylenehexamine Additional Information The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16. All Concentration values are expressed in a weight/weight % value. Although Isopropanol is listed here as being flammable, This is not evident at these concentrations. 4. FIRST AID MEASURES   General - If medical attention is required present a copy of this datasheet to the physician.   Remove all contaminated clothing. The person must rest and be kept under medical   observation even if there are no immediate signs of symptoms. Define a first aid plan   of action prior to commencing work with this product. Consult the occupational   physician. Inhalation - Not usually considered to be harmful by inhalation. If symptoms arise, remove affected   person to fresh air and keep at rest. If breathing is irregular or has stopped, administer   artificial respiration. Seek medical attention Skin Contact - Flood skin with large quantites of water whilst removing contaminated clothing, The   product may remain trapped under clothing, footwear or a wrist watch. Seek medical attention Eye Contact - Immediately wash eyes with plenty of water while lifting the eye lids. Continue to rinse   for at least 15 minutes. Seek  medical attention Ingestion - Do NOT induce vomiting. If swallowed, seek medical advice immediately and show the   container or label. Keep person warm and at rest. Seek medical attention immediately Common Symptoms and effects both acute and delayed Inhalation - No known symptoms. Ingestion - May gause Gastric and Intestinal problems. Skin Contact - Prolonged or repeated contact may cause irritation, redness, dry skin, cracking and   dermatitis. Eye Contact - Symptoms may include irritation or pain, lacrimation and redness of the eye tissue.  5. FIRE FIGHTING MEASURES   Fire Hazards - In a fire or if heated, a pressure increase may burst containers. Not flammable   under normal conditions. Extinguishing Media - Carbon Dioxide, Dry Chemical, Powder or Water in a fog. Combustion Products - During fire, oxides of Carbon and Nitrogen are formed. Protective Equipment - Self contained breathing apparatus and full protective clothing must be worn   in case of fire. Environmental - Keep run off water out of sewers and water sources. Dike for water control. Procedures - Stay upwind, evacuate personnel, use suitable extinguishers. Move containers   from fire area if it can be done without risk. Withdraw immediately in case of   rising sound from venting safety device (if present) or any discoloration of tanks   occur due to fire. Use water spray to control vapours. If risk of water pollution   occurs, notify appropriate authorities. 6. ACCIDENTAL RELEASE MEASURES   Personal - Use protective clothing suitable for handling product (see sec. 8). Avoid contact   with skin and eyes. Restrict access to authorised personnel. Stay upwind. Environmental - Do not allow to enter into surface water or sewer system. If product enters   drains, inform the Envonmental Agency. Methods of Clean Up - Ventilate well, stop flow of gas or liquid if possible. Absorb in vermiculite, dry   sand or earth and place in containers. Dispose of in accordance with local   legislation.   7. HANDLING AND STORAGE   Handling - Avoid creating dusty conditions. Good industrial practice in housekeeping and personal   hygiene should be followed. When using do not eat, drink or smoke. Wear suitable gloves   and eye/face protection. (See 8). Equipment or utensils used for dispensing the product must   be suitable for the purpose. Wash out after use. Wash thoroughly after handling the material.   Remove contaminated clothing and wash before re-use. Avoid contact with eyes, skin and   clothing. Avoid ingestion. Emergency eye wash stations and showers should be made   available. Storage - Store in a dry ventilated area. Reseal open packages to prevent spillage. Keep containers   tightly closed. Keep away from oxidising substances. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION   Adequate ventilation should be provided such that Derived No Effect Limits are not exceeded. Local Exhaust Ventilation is preferable to personal protection. Gloves made out of Butyl Rubber at least 0.5mm thick, goggles, protective overalls and chemically resistant safety shoes should also be worn. Provide eyewash station and safety shower. Wear appropriate clothing to prevent repeated or prolonged skin contact. Note, these DNEL and PNECs are for the hazardous components and not the product as a whole, This product contains less than 3% Isopropanol. DNEL Chronic = Long Term Exposure Inhalation (mg / m³) Oral (mg/kg  bw/day) Dermal (mg/kg bw/day) Information provided by echa PNEC Hygiene Measures   Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet. Remove any clothing that becomes wet or contaminated. Contaminated clothing should be placed in a closed container until disposal or decontamination. Warn cleaning personnel of contaminants hazardous properties. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY   Conditions to Avoid - None Materials to Avoid - Strong oxidizing agents, strong acids. Hazardous decomp products - Does not decompose under normal conditions. When burned, produces   oxides of carbon and nitrogen. 11.  TOXILOGICAL  INFORMATION   General - Not classified as Toxic. Skin Contact - Prolonged or repeated contact causes irritation which may lead to   dermatitis or skin cracking. Eye Contact - May cause irritation to eyes. Inhalation - Not known to be harmful by inhalation. Does not produce vapours at STP. Ingestion - May cause nausea and vomiting. Ingesting large quantites may lead to   kidney failure. Toxilogical information on ingredients Information provided is for ingredients at full concentration, and not at the concentration present in Q19. 12.  ECOLOGICAL  INFORMATION   Q19  is not considered to be dangerous to the environment or toxic to fish. Ecological information on ingredients (Acute Toxicity) Information provided is for ingredients at full concentration, and not at the concentration present in the product. Persistence and degradability   There is no data on the degradability of this product. Bioaccumulative potential There are no data on the bioaccumulation of this product. Mobility in soil There are no data on the Mobility in soil of this product. PBT and vPvB assessment This product does not contain any PBT or vPvB substances. 13. DISPOSAL CONSIDERATIONS   Hazardous Waste. Contact specialist disposal companies. Dispose of waste and residues in accordance with local authority requirements. Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste collection point. Contact waste disposal services. 14. TRANSPORT INFORMATION Polybond Q19 is not regulated for Transport. 15. REGULATORY INFORMATION   Statutory Instruments Control of Substances Hazardous to Health. Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 th  December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 th  December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. National Regulations Control of Substances Hazardous to Health Regulations 2002 (as amended) The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 ("CDG 2009"), SI 2009 No 1348. 16. OTHER INFORMATION Abbreviations: N/A not applicable. ND not determined. NR not regulated. ADR: European agreement concerning the international carriage of Dangerous goods by road. CAS International reference numbers for chemical substances. (Chemical Abstracts Service) CHIP: Chemicals (Hazard Information and Packaging) Regulations 1993, and later revisions. DNEL: Derived No-Effect Level. EINECS: European Inventory of Existing commercial Chemical Substances. GHS: Globally Harmonized System of Classification and Labelling of Chemicals. HSE EH40: H.S.E. Guidance note EH40 on Occupational Exposure Limits (revised annually), to be used in conjunction with the COSHH regulations. IMDG: International Maritime code for Dangerous Goods. LC50: Lethal Concentration, 50 percent. LD50: Lethal Dose, 50 percent. EC50: Concentration of toxant that provides a response that is half way between a baseline and maximum effect. IC50: Concentration that is half way between a baseline and completely inhibiting a biological function. LL50: Similar to LC 50 but tests the water phase from incompletely miscible materials. EL50: Similar to EC 50 but tests the water phase from incompletely miscible materials. PBT: Persistent Bioaccumulative Toxic. PNEC: Predicted No-Effect Concentration. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. STEL: Short Term Exposure Limit. STP: Standard Temperature and Pressure, in a standard environment (298°K / 25°C and 1 atm pressure) TWA: Time Weighted Average. vPvB: Very Persistent and Very Bioaccumulative. WEL: Workplace Exposure Limit. Example Label using information from Section 2.2 Risk Phrases From Section 2.1 and 3 in Full R11 Highly flammable. R36 Irritating to eyes. R67 Vapours may cause drowsiness and dizziness. R36/38 Irritating to eyes and skin. Hazard Statements From Section 2.1 and 3 in Full H225 Highly flammable liquid and vapour. H315 Causes skin irritation. H318 Causes serious eye damage. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness.

Updated: November 2015

Note: This data sheet does not constitue a user's assessment of workplace risk as required by the Health & Safety At Work Act, COSHH, Management of Health and Safety at Work Regulations or other health and safety legislation The data contained in this safety data sheet has been supplied as required by the Chemicals (Hazard identification and Packaging for supply) Regulations, as amended, for the purpose of protecting the health and safety of industrial users who are deemed capable of understanding and acting upon the information provided. Every endeavour has been made to ensure that the information in this document is reliable, but no responsibility can be taken for errors or omissions.  Users must satisfy themselves that there are no circumstances requiring additional information or precautions or the verification of details given herein.