Polybond Ltd. Unit 6, William Street, Northam, Southampton, SO14 5QH Tel: 02380 988350    Fax: 02380 988355

Polybond Hi-Grip - Health and Safety Datasheet 1. IDENTIFICATION OF SUBSTANCE Product Name Polybond Hi Grip Product Description A plasticiser-free water-based co-polymer dispersion. Supplier As heading   2.1 CLASSIFICATION OF THE SUBSTANCES OR MIXTURE EC 1272/2008 Physical and Chemical Hazards None Human health Acute Tox. 4 - H302, Repr.2 - H361, Muta 1B - H340 Carc 1 - H350 Environment Aquatic Chronic 3 - H412 The Full Text for all Hazard Statements are Displayed in Section 16. Human health The product may be harmful if swallowed. This product contains a small proporion or a product that is suspected of causing cancer, and may cause genetic defects. Physical and Chemical Hazards None 2.2 LABEL ELEMENTS Contains Naphtha Labels in Accordance with EC 1272/2008 Signal Word Danger Hazard Statements H302 Harmful if swallowed. H361 Suspected of damaging fertility or the unborn child. H340 May cause genetic defects. H350 May cause cancer. H412 Harmful to aquatic life with long lasting effects. Precautionary Statements P273 Avoid release to the environment. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301 + P310 IF SWALLOWED: Immediately call a doctor. P331 Do NOT induce vomiting. 3. COMPOSITION / INFORMATION ON INGREDIENTS     Additional Information The Full Text for all Hazard Statements are Displayed in Section 16. All Concentration values are expressed in a weight/weight % value. 4. FIRST AID MEASURES   General - If medical attention is required present a copy of this datasheet to the physician.   Remove all contaminated clothing. The person must rest and be kept under medical   observation even if there are no immediate signs of symptoms. Define a first aid plan   of action prior to commencing work with this product. Consult the occupational   physician. Inhalation - Remove affected person to fresh air and keep at rest. Do not leave affected person   unattended. If breathing is diffcult, give oxygen if possible or assisted ventilation. If   unconcious, place in recovery position. Skin Contact - Flood skin with large quantites of soap and water whilst removing contaminated clothing.   Wash for at least 15 minutes. The product may remain trapped under clothing, footwear or   a wrist watch. Eye Contact - Remove contact lenses. Immediately wash eyes with plenty of water while lifting the   eye lids. Continue to rinse for at least 15 minutes. If there are signs of irritation or other   symptoms seek medical attention. Seek medical attention Ingestion - Do NOT induce vomiting, if vomiting does occur, have affected person lean forward to   reduce risk of aspiration. If swallowed, seek medical advice immediately and show the   container or label. Clean mouth with water and drink plenty of water. Do not give milk   or alcoholic beverages. Never give anything by mouth to an unconscious person. Keep   person warm and at rest. Seek medical attention immediately Common Symptoms and effects both acute and delayed Inhalation - No known acute for chronic symptoms. Ingestion - Symptoms may include nausea and vomiting. Skin Contact - No known acute for chronic symptoms. Eye Contact - Symptoms may include irritation or pain, lacrimation and redness of the eye tissue.  5. FIRE FIGHTING MEASURES   Fire Hazards - In a fire or if heated, a pressure increase may burst containers. The vapour/gas   is heavier than air and will spread along the ground. Extinguishing Media - If a large fire, use water spray, water fog or foam. do not use water as a jet.   If a small fire, use Carbon Dioxide, Dry Chemical, Powder, Dry sand or Foam. Combustion Products - During fire, oxides of Carbon and smoke are formed. Protective Equipment - Self contained breathing apparatus and full protective clothing must be worn   in case of fire. Environmental - Keep run off water out of sewers and water sources. Dike for water control. Procedures - Stay upwind, evacuate personnel, use suitable extinguishers. Use water spray   to control vapours. If risk of water pollution occurs, notify appropriate authorities. 6. ACCIDENTAL RELEASE MEASURES   Personal - Use protective gloves, goggles and suitable protective clothing. Environmental - Do not allow to enter into surface water or sewer system. Methods of Clean Up - Ventilate well, stop flow of gas or liquid if possible. Remove ignition sources.   Absorb in vermiculite, dry sand or earth and place in containers. Dispose of in   accordance with local legislation.   7. HANDLING AND STORAGE   Handling - Good industrial practice in housekeeping and personal hygiene should be followed. When   using do not eat, drink or smoke. Wear suitable gloves and eye/face protection. (See 8).   Equipment or utensils used for dispensing the chemical must be suitable for the purpose.   Wash out after use. Wash thoroughly after handling the material. Remove contaminated   clothing and wash before re-use. Avoid contact with eyes. Avoid ingestion/inhalation.   Emergency eye wash stations and showers should be made available. Storage - Store in a dry ventilated area. Reseal open packages to prevent spillage. Keep containers   tightly closed. Keep away from oxidising substances. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION   Adequate ventilation should be provided such that Derived No Effect Limits are not exceeded. Local Exhaust Ventilation is preferable to personal protection. Gloves made out of Butyl Rubber at least 0.5mm thick, goggles, protective overalls, a chemical respirator and chemically resistant safety shoes should also be worn. Provide eyewash stations. Wear appropriate clothing to prevent repeated or prolonged skin contact. There are no DNELs or PNECs available for the only hazardous component in Hi-Grip. Hygiene Measures   Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet. Remove any clothing that becomes wet or contaminated. 9. PHYSICAL AND CHEMICAL PROPERTIES 10. STABILITY AND REACTIVITY   Conditions to Avoid - None. Materials to Avoid - None. Hazardous decomp products - Does not decompose under normal conditions. When heated, produces   oxides of carbon and water. 11.  TOXILOGICAL  INFORMATION   General - None. Skin Contact - Prolonged or repeated contact causes irritation which may lead to   dermatitis. Eye Contact - May cause irritation to eyes. Inhalation - None. Ingestion - May cause nausea and vomiting. Ingesting large quantites may lead to   kidney failure. Toxilogical information on ingredients 12.  ECOLOGICAL  INFORMATION   Polybond Hi Grip is classified as harmful to the aquatic environment. Ecological information on ingredients (Acute Toxicity) Persistence and degradability   There is no data on the degradability of this product. Bioaccumulative potential There are no data on the bioaccumulation of this product. Mobility in soil There are no data on the Mobility in soil of this product. PBT and vPvB assessment This product does not contain any PBT or vPvB substances. 13. DISPOSAL CONSIDERATIONS   Hazardous Waste. Contact specialist disposal companies. Dispose of waste and residues in accordance with local authority requirements. Absorb in vermiculite or dry sand and dispose of at a licenced hazardous waste collection point. Contact waste disposal services. 14. TRANSPORT INFORMATION 15. REGULATORY INFORMATION   Statutory Instruments Control of Substances Hazardous to Health. Approved Code Of Practice Safety Data Sheets for Substances and Preparations. Classification and Labelling of Substances and Preparations Dangerous for Supply. Guidance Notes Workplace Exposure Limits EH40. EU Legislation Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 th  December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 th  December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. National Regulations Control of Substances Hazardous to Health Regulations 2002 (as amended) The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2009 ("CDG 2009"), SI 2009 No 1348. 16. OTHER INFORMATION Abbreviations: N/A not applicable. ND not determined. NR not regulated. ADR: European agreement concerning the international carriage of Dangerous goods by road. CAS International reference numbers for chemical substances. (Chemical Abstracts Service) CHIP: Chemicals (Hazard Information and Packaging) Regulations 1993, and later revisions. DNEL: Derived No-Effect Level. EINECS: European Inventory of Existing commercial Chemical Substances. GHS: Globally Harmonized System of Classification and Labelling of Chemicals. HSE EH40: H.S.E. Guidance note EH40 on Occupational Exposure Limits (revised annually), to be used in conjunction with the COSHH regulations. IMDG: International Maritime code for Dangerous Goods. LC50: Lethal Concentration, 50 percent. LD50: Lethal Dose, 50 percent. NOEC: No Effect Concentration. EC50: Concentration of toxant that provides a response that is half way between a baseline and maximum effect. IC50: Concentration that is half way between a baseline and completely inhibiting a biological function. LL50: Similar to LC 50 but tests the water phase from incompletely miscible materials. EL50: Similar to EC 50 but tests the water phase from incompletely miscible materials. PBT: Persistent Bioaccumulative Toxic. PNEC: Predicted No-Effect Concentration. RID: Regulation Concerning the International Transport of Dangerous Goods by Rail. STEL: Short Term Exposure Limit. STP: Standard Temperature and Pressure, in a standard environment (298°K / 25°C and 1 atm pressure) TWA: Time Weighted Average. vPvB: Very Persistent and Very Bioaccumulative. WEL: Workplace Exposure Limit. Example Label using information from Section 2.2 Hazard Statements in Full H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H336 May cause drowsiness or dizziness. H340 May cause genetic defects. H361 Suspected of damaging fertility or the unborn child. H411 Toxic to aquatic life with long lasting effects.

Updated: April 2017

Note: This data sheet does not constitue a user's assessment of workplace risk as required by the Health & Safety At Work Act, COSHH, Management of Health and Safety at Work Regulations or other health and safety legislation The data contained in this safety data sheet has been supplied as required by the Chemicals (Hazard identification and Packaging for supply) Regulations, as amended, for the purpose of protecting the health and safety of industrial users who are deemed capable of understanding and acting upon the information provided. Every endeavour has been made to ensure that the information in this document is reliable, but no responsibility can be taken for errors or omissions.  Users must satisfy themselves that there are no circumstances requiring additional information or precautions or the verification of details given herein.